徐闻南山镇红树林沉积物及红树植物中重金属的累积特征与迁移规律

为探究重金属在红树林沉积物及红树植物中的分布累积及迁移规律，选取了徐闻南山镇红树林为研究对象，通过测定红树林沉积物及红树植物不同部位（根、茎、叶）的重金属质量分数，运用富集因子、生物富集系数、转移系数及相关性分析等方法进行分析。结果表明：1）红树林沉积物重金属质量分数表现为铬（Cr）＞锌（Zn）＞镍（Ni）＞铜（Cu）＞铅（Pb）＞砷（As）＞汞（Hg）＞镉（Cd），为中等变异程度；除了镍（Ni）元素外，其余7种重金属未超过国家一级标准，除了铅（Pb）元素外，其余7种重金属均超过广东省土壤环境背景值，说明研究区沉积物中重金属具有一定的积累效应。2）沉积物中砷（As）、铜（Cu）、锌（Zn）、汞（Hg）、镍（Ni）、铬（Cr）富集因子值均＞1.5，说明受到轻微人为活动影响；各站位镍（Ni）富集因子值均＞5，结合研究区背景，反映了镍（Ni）受到自然和人为输入的共同影响。3）白骨壤体内重金属主要集中在根部，而红海榄体内重金属在根茎叶中分布相对均匀。白骨壤根茎叶部位的大多数重金属质量分数远高于红海榄，说明白骨壤对重金属的吸附能力比红海榄强。汞（Hg）集中分布在植物的叶片部位，且与其他重金属之间相关性不明显；推测汞（Hg）主要通过叶片吸收进入植物体内，与交通运输污染有关。4）不同红树植物对不同重金属富集能力各异，白骨壤对重金属的富集能力表现为：镉（Cd）＞砷（As）＞铜（Cu）＞锌（Zn）＞汞（Hg）＞铅（Pb）＞镍（Ni）＞铬（Cr），红海榄表现为：镉（Cd）＞铜（Cu）＞汞（Hg）＞锌（Zn）＞铅（Pb）＞砷（As）＞镍（Ni）＞铬（Cr）。白骨壤和红海榄对汞（Hg）的运移能力都较强；红海榄对镉（Cd）的富集能力和转运能力都较强，而白骨壤对镉（Cd）富集能力较强，转运能力却较弱，这说明红树植物对重金属元素的富集能力与转运能力不存在正比关系。     

经济地理学视角下创新网络与区域增长研究述评

创新是引领经济发展的第一动力，创新与区域增长之间的关系成为经济地理学者关注的重点领域。文章通过梳理近年来有关创新网络测度、创新网络与区域增长关系、创新网络作用于区域增长方式等方面的文献发现：网络资本可以弥补社会资本在解释企业创新结网经济价值方面的不足，区域增长呈现出网络化特征已成为学界共识，知识流与邻近性能较好地解释创新网络与区域增长的关系机理。然而，当前研究对社会资本如何促进区域增长，网络资本与区域增长关系模型如何构建，不同类型的邻近性与知识对区域增长的影响有何差异等问题尚不明确，建议重视网络资本对区域增长的作用并实证检验二者的关联，同时还应重视创新网络中企业家精神、创新个体心理行为特征等因素对区域增长的影响。     

Anthropogenic trace metals in an ice core at Vestfonna,Svalbard, Norway

1　IntroductionAnicecoreobtainedfrom polarglaciersoricesheetsisoneofthemostimportantarchivestoreconstructpaleoclimaticandpaleoatmosphericcondition .Informationonpale o environmentcanbeextractedfromicecoresaschemicaland/orphysicalsignals.Amongthechemicalsignals,heavymetalsarenotedassignalsofterrestrialenvironmentalchangeandanthropogenicpollution (e.g .Murozumietal.1 969;NgandPatterson 1 981 ;Hongetal.1 994) .SinceconcentrationsofmostofthemetalsinpolarsnowincentralGreen landareatorbelowthepptl…     

REGIONAL DEMOGRAPHIC STRUCTURE OF THE UNITED STATES

This paper analyzes the surprisingly great variation in demographic character across the states, utilizing data on fertility, mortality, age, sex, mobility, household character, abortion, race and ethnicity. A fairly simple regional pattern is revealed that is less related to levels of economic development than to long-standing historical cultural differences.     

DEVELOPMENT STRATEGIES OF WATER AND LAND RESOURCES IN THE HEXI REGION,CHINA

ＤＥＶＥＬＯＰＭＥＮＴＳＴＲＡＴＥＧＩＥＳＯＦＷＡＴＥＲＡＮＤＬＡＮＤＲＥＳＯＵＲＣＥＳＩＮＴＨＥＨＥＸＩＲＥＧＩＯＮ，ＣＨＩＮＡ肖洪浪，高前兆，李福兴ＤＥＶＥＬＯＰＭＥＮＴＳＴＲＡＴＥＧＩＥＳＯＦＷＡＴＥＲＡＮＤＬＡＮＤＲＥＳＯＵＲＣＥＳＩＮＴＨＥ...     

The stable isotope signature of kilometre-scale fracturedominated metamorphic fluid pathways, Mary Kathleen, Australia

Abstract Large calcite veins and pods in the Proterozoic Corella Formation of the Mount Isa Inlier provide evidence for kilometre-scale fluid transport during amphibolite facies metamorphism. These 10- to 100-m-scale podiform veins and their surrounding alteration zones have similar oxygen and carbon isotopic ratios throughout the 200 × 10-km Mary Kathleen Fold Belt, despite the isotopic heterogeneity of the surrounding wallrocks. The fluids that formed the pods and veins were not in isotopic equilibrium with the immediately adjacent rocks. The pods have δ¹³C_calcite values of –2 to –7% and δ¹⁸O_calcite values of 10.5 to 12.5%. Away from the pods, metadolerite wallrocks have δ¹⁸O_whole-rock values of 3.5 to 7%. and unaltered banded calc-silicate and marble wallrocks have δ¹³C_calcite of –1.6 to –0.6%, and δ¹⁸O_calcite of 18 to 21%. In the alteration zones adjacent to the pods, the δ¹⁸O values of both metadolerite and calc-silicate rocks approach those of the pods. Large calcite pods hosted entirely in calc-silicates show little difference in isotopic composition from pods hosted entirely in metadolerite. Thus, 100- to 500-m-scale isotopic exchange with the surrounding metadolerites and calc-silicates does not explain the observation that the δ¹⁸O values of the pods are intermediate between these two rock types. Pods hosted in felsic metavolcanics and metasiltstones are also isotopically indistinguishable from those hosted in the dominant metadolerites and calc-silicates. These data suggest the veins are the product of infiltration of isotopically homogeneous fluids that were not derived from within the Corella Formation at the presently exposed crustal level, although some of the spread in the data may be due to a relatively small contribution from devolatilization reactions in the calc-silicates, or thermal fluctuations attending deformation and metamorphism. The overall L-shaped trend of the data on plots of δ¹³C vs. δ¹⁸O is most consistent with mixing of large volumes of externally derived fluids with small volumes of locally derived fluid produced by devolatilization of calc-silicate rocks. Localization of the vein systems in dilatant sites around metadolerite/calc-silicate boundaries indicates a strong structural control on fluid flow, and the stable isotope data suggest fluid migration must have occurred at scales greater than at least 1 km. The ultimate source for the external fluid is uncertain, but is probably fluid released from crystallizing melts derived from the lower crust or upper mantle. Intrusion of magmas below the exposed crustal level would also explain the high geothermal gradient calculated for the regional metamorphism.     

An approach to quantitative analysis of regional economic links

Aimed at promoting regional coalitions and expanding the approach to economic links, this paper puts forward some new concepts such as link intensity and receiving coefficient, expounds the indexes of quantitative analysis of economic links and establishes the quantitative-analysis model of economic links. With help of the model, this paper calculates the values of the link intensities between Su-Xi-Chang (Suzhou-Wuxi-Changzhou) region and Shanghai, and analyzes the regional difference of the economic links.     

Infiltration at the Tai rain forest (Ivory Coast): Measurements and modelling

Infiltration experiments have been performed at three sites along a well-known catena under virgin tropical rain forest using a portable sprinkling infiltrometer. Experimentally determined infiltration curves are presented. Infiltration curves are also simulated on the basis of the Mein-Larson equation. The parameters for this model have been obtained from the infiltration curves (saturated conductivity) and simple soil moisture determinations (fillable porosity). The agreement between experimentally determined and modelled infiltration is reasonable, provided (a) saturated conductivity as derived from the experimental data is corrected, (b) a storage parameter, also derived from the experimental data, is added to the Mein-Larson model, and (c) the decline in soil porosity with depth is either small or occurs abruptly at shallow depth. Comparison of observed infiltration rates with rainfall intensity shows that Horton Overland Flow has to occur naturally at least on the middle and lower section of the catena. Despite the fact that most parameters can be estimated in principle from basic soil data, it remains advisable to obtain sprinkling infiltrometer field measurements, because of soil variability due to dynamic surface conditions, macroporosity, air entrapment, and irregularity of the wetting front.     

Hysteresis‐based analysis of overland metal transport

Introducing a concept of equivalent mass depth of flow, this study describes the phenomenon of non‐point source pollutant (metal) transport for pavement (or overland) flow in analogy with wave propagation in wide open channels. Hysteretic and normal mass rating curves are developed for runoff rate and mass of 12 dissolved and particulate‐bound metal elements (pollutants) using the rainfall‐runoff and water quality data of the 15 × 20 m² instrumented pavement in Cincinnati, USA. Normal mass rating curves developed for easy computation of pollutant load are found to be of a form similar to Manning's, which is valid for open channel flows. Based on the hysteresis analysis, wave types for dissolution and mixing of particulate‐bound metals are identified. The analysis finds that the second‐order partial‐differential equation normally used for metal transport does not have the efficacy to describe fully the strong non‐linear phenomena such as is described for various metal elements by dynamic waves. In addition, the proportionality concept of the popular SCS‐CN concept is extended for determining the potential maximum metal mass M_p of all the 12 elements transported by a rain storm and related to the antecedent dry period (ADP). For the primary metal zinc element, M_p is found to increase with the ADP and vice versa. Copyright © 2003 John Wiley & Sons, Ltd.